Talking about batteries with fellow RVers will no doubt bring up at least a mention of RV lithium batteries. Many people have heard of them. They are supposedly the latest and greatest in RV battery power. Advertise. Batteries, at their basic level, are simple devices. They contain two types of metals submerged in an electrolyte solution. A separator keeps the metals from touching, but ions and the. The lead-acid battery is still the battery of choice for cars and RVs. Most RVers still preferred them. They rely on inexpensive components, and therefore, it is a relatively cheap battery. T. There are two types of lead-acid batteries typically used in RVs. Starter batteries deliver a large burst of power quickly. Deep cycle batteries give off a lower amount of power over a lon. The energy density of lithium batteries is much higher than that of lead-acid batteries. This means more energy can be stored in a smaller space. It also means an RV lithium batter.